E-kilipaalu

[mikar]

Miksi ei vaikuta?

http://gmwgroup.harvard.edu/pubs/pdf/1109.pdf

Externally Applied Electric Fields up to 1.6 x 10 5 V/m Do Not Affect the Homogeneous Nucleation of Ice in Supercooled Water

Miten setup fig 3.?

"The field-induced freezing predicted by simulations cannot be investigated in experiments with bulk samples of water, because the magnitude of the electric field exceeds the dielectric breakdown strength of pure water."

Voiskos tämän jotenkin ratkaista?

[mikar]

Entäs auttaako tietokonesimulaatiot?

Review 2011, aukeaa oikealla sivulla olevasta pdf-linkistä

http://www.neutron-sciences.org/index.p ... 12009.html


- sivulla 5: An important point to note is that in condensed phases there are polarization effects that cannot be fully described using fixed partial charges.

- sivulla 7: Incorporating polarization effects into the potential describing the intermolecular interactions is an important step forward. However a force field is a global entity, so the construction of new polarizable force fields requires also a reoptimization of the Van der Waals and intramolecular parameters. This represents a huge task, so
current polarizable force fields have not yet achieved a fully mature state.

- sivulla 8: This has led T. Halgren to say that “force field development is still as much a matter of art as of science” [82].


Eli ei oikein sieltä ratkaisua löydy.

[mikar]

Mitäs tuossa kuvassa ja videossa tapahtuu



videossa puolen välin aikaan + ja - vaihdettu

http://www.youtube.com/watch?v=5c5kOGlP5dA

[mikar]

Kukas tämän sanoi ja teki aikaisemmin

Liquid Can Turn Into Solid Under High Electric Field, Physicists Show in Simulations (Oct. 11, 2011)

Physicists have predicted that under the influence of sufficiently high electric fields, liquid droplets of certain materials will undergo solidification, forming crystallites at temperature and pressure conditions that correspond to liquid droplets at field-free conditions. This electric-field-induced phase transformation is termed electrocrystallization.

http://www.sciencedaily.com/releases/20 ... 112913.htm

jussik5, kukas tämän ketjun eka linkin artikkelin kirjoittaja olikaan, olikos nimi sulla jollakin listalla

[jussik5]

Ei muistu mieleen vastausta eka kyssäriin.

Mutta toka: Noopelit jaossa listalta löytyy tällaanen herrasmies
http://en.wikipedia.org/wiki/George_M._Whitesides
Oli paperissa vetäny ittensä vastaavaks.

[mikar]

Pitäisi saada jotenkin järjestykseen, on kokeiltu ultraääntä, mikroaaltoja, magneetteja, milläs nämä saisi säädettyä haluttuun muotoon

Dense liquid precursor for the nucleation of ordered solid phases from solution
http://pubs.acs.org/doi/abs/10.1021/cg049977w